51视频

Universal Journal of Chemistry(CEASE PUBLICATION) Vol. 3(1), pp. 10 - 15
DOI: 10.13189/ujc.2015.030102
Reprint (PDF) (213Kb)

Synthesis and Characterization of Symmetrical and Unsymmetrical Analogues of 1,2-bis[bis(4-chlorophenyl) Methyl] Diselane

Rajeev Kumar ^*
Department of Environment Studies, Panjab University, India

ABSTRACT

The 'living' species selenide anion Se₂^2-, generated in situ by the reduction of 1,2-bis(bis(4-chlorophenyl)methyl)diselane with sodium borohydride, was treated with various organic halides to afford synthetically important organoselenium compounds including 伪,蠅-diselenoethers and selenides bearing ester functionality, under mild and neutral conditions. These compounds have been characterized analytically with the help of various spectroscopic techniques viz., IR, multinuclear NMR (¹H, ¹³C, ⁷⁷Se) and mass spectrometry.

KEYWORDS
Selenide, Diselenide, Symmetrical Diselenide, Unsymmetrical Selenide, Selenoether

Cite This Paper in IEEE or APA Citation Styles
(a). IEEE Format:
[1] Rajeev Kumar , "Synthesis and Characterization of Symmetrical and Unsymmetrical Analogues of 1,2-bis[bis(4-chlorophenyl) Methyl] Diselane," Universal Journal of Chemistry(CEASE PUBLICATION), Vol. 3, No. 1, pp. 10 - 15, 2015. DOI: 10.13189/ujc.2015.030102.

(b). APA Format:
Rajeev Kumar (2015). Synthesis and Characterization of Symmetrical and Unsymmetrical Analogues of 1,2-bis[bis(4-chlorophenyl) Methyl] Diselane. Universal Journal of Chemistry(CEASE PUBLICATION), 3(1), 10 - 15. DOI: 10.13189/ujc.2015.030102.