Journals Information
Universal Journal of Chemistry(CEASE PUBLICATION) Vol. 3(2), pp. 49 - 54
DOI: 10.13189/ujc.2015.030201
Reprint (PDF) (319Kb)
The Influence of Irradiation and Temperature to the Nature of Crosslinking in Isoprene Nitrile Elastomer
Shiraz M. Mammadov *, Rena F. Khankisiyeva , Jovdat S. Mammadov , Adil A. Garibov , Revan N. Mehdiyeva
Institute of Radiation Problems, Azerbaijan National Academy of Sciences, Azerbaijan
ABSTRACT
The increase of irradiation temperature by gamma-rays of emulsion isoprene nitrile elastomer in the range of 298-423 K is accompanied by the significant increase of crosslinking rate and strength deterioration of unfilled cures at the same time. By the method of sol-gel analysis, the output dependences of the mesh chains (1/Mc), cross-linked molecules (1/M茷t) and crosslinks (nc) for isoprene nitrile elastomer are determined between 298 and 423 K. The influence of acrylonitrile content of elastomer group during the process of irradiation and temperature on density change of curing grid using Fourier spectroscopy is established. It also studied the molecular structure of isoprene nitrile elastomer and unsaturation at irradiation and temperature (423K, 500 kGy).
KEYWORDS
Isoprene Nitrile Rubber, Irradiation, Crosslinking, Temperature, Rheology, Curing
Cite This Paper in IEEE or APA Citation Styles
(a). IEEE Format:
[1] Shiraz M. Mammadov , Rena F. Khankisiyeva , Jovdat S. Mammadov , Adil A. Garibov , Revan N. Mehdiyeva , "The Influence of Irradiation and Temperature to the Nature of Crosslinking in Isoprene Nitrile Elastomer," Universal Journal of Chemistry(CEASE PUBLICATION), Vol. 3, No. 2, pp. 49 - 54, 2015. DOI: 10.13189/ujc.2015.030201.
(b). APA Format:
Shiraz M. Mammadov , Rena F. Khankisiyeva , Jovdat S. Mammadov , Adil A. Garibov , Revan N. Mehdiyeva (2015). The Influence of Irradiation and Temperature to the Nature of Crosslinking in Isoprene Nitrile Elastomer. Universal Journal of Chemistry(CEASE PUBLICATION), 3(2), 49 - 54. DOI: 10.13189/ujc.2015.030201.