Journals Information
Universal Journal of Chemistry(CEASE PUBLICATION) Vol. 3(2), pp. 55 - 59
DOI: 10.13189/ujc.2015.030202
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Electrochemical Reduction of Nickel 鈥� acrylic Acid Complexes: Quantum-chemical Analysis
Viktor F. Vargalyuk 1, Vladimir A. Polonskyy 1, Larissa V. Borshchevych 1, Oksana V. Demchyshyna 2,*
1 Department of Chemistry, Oles Honchar Dnipropetrovsk National University, Ukraine
2 State Institution of Higher Education, Kryvyi Rih National University, Ukraine
ABSTRACT
On the basis of quantum-chemical cluster calculations [Niz+ (H2O) nL](H2O)5-n in the interval z = +2, +1, 0 and n = 0, 1-5 the mechanism of electroreduction of complexes of Ni2+ and acrylic acid (HAk) has been proved. It has been demonstrated that the initial reactant is the [Ni2+(H2O)5Ak鈥�], the intermediate is the [Ni+ (H2O)2Ak鈥�] and the end product exists in various forms among which the most stable is [Ni0(H2O)2(蟺-贬袗办)闭.
KEYWORDS
Complexes of Nickel, Acrylic Acid, The Mechanism of Electroreduction, Quantum-chemical Modeling
Cite This Paper in IEEE or APA Citation Styles
(a). IEEE Format:
[1] Viktor F. Vargalyuk , Vladimir A. Polonskyy , Larissa V. Borshchevych , Oksana V. Demchyshyna , "Electrochemical Reduction of Nickel 鈥� acrylic Acid Complexes: Quantum-chemical Analysis," Universal Journal of Chemistry(CEASE PUBLICATION), Vol. 3, No. 2, pp. 55 - 59, 2015. DOI: 10.13189/ujc.2015.030202.
(b). APA Format:
Viktor F. Vargalyuk , Vladimir A. Polonskyy , Larissa V. Borshchevych , Oksana V. Demchyshyna (2015). Electrochemical Reduction of Nickel 鈥� acrylic Acid Complexes: Quantum-chemical Analysis. Universal Journal of Chemistry(CEASE PUBLICATION), 3(2), 55 - 59. DOI: 10.13189/ujc.2015.030202.