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Universal Journal of Chemistry(CEASE PUBLICATION) Vol. 3(2), pp. 80 - 85
DOI: 10.13189/ujc.2015.030205
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Using the Reactions O+H2 → OH+H to Explore the Importance of the Atomic Quantum States on Chemical Kinetics and Reaction Dynamics


João Brandão , Wenli Wang , Carolina M. A. Rio *
CIQA, Department of Chemistry and Pharmacy, Faculty of Science and Technology, University of the Algarve, Campus of Gambelas, Portugal

ABSTRACT

The O + H2 reaction is a particular example to alert the importance of a clear definition of the quantum state of an atom when referring to a chemical reaction. In its ground state, O (3P), the oxygen atom reacts with H2 through an energy barrier with small rate constant. In contrast, when the oxygen atom is in its first excited state, O (1D), the reaction O + H2 occurs without energy barrier and the rate constant is seven orders of magnitude higher. The dynamic behaviour of this reaction depends also on the quantum state of the oxygen atom.

KEYWORDS
Quantum State, Rate Constant

Cite This Paper in IEEE or APA Citation Styles
(a). IEEE Format:
[1] João Brandão , Wenli Wang , Carolina M. A. Rio , "Using the Reactions O+H2 → OH+H to Explore the Importance of the Atomic Quantum States on Chemical Kinetics and Reaction Dynamics," Universal Journal of Chemistry(CEASE PUBLICATION), Vol. 3, No. 2, pp. 80 - 85, 2015. DOI: 10.13189/ujc.2015.030205.

(b). APA Format:
João Brandão , Wenli Wang , Carolina M. A. Rio (2015). Using the Reactions O+H2 → OH+H to Explore the Importance of the Atomic Quantum States on Chemical Kinetics and Reaction Dynamics. Universal Journal of Chemistry(CEASE PUBLICATION), 3(2), 80 - 85. DOI: 10.13189/ujc.2015.030205.