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Energy and Environmental Engineering(CEASE PUBLICATION) Vol. 1(3), pp. 99 - 104
DOI: 10.13189/eee.2013.010301
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Lead (II)-Selective Polymeric Electrode Using PVC Membrane Based on a Schiff Base Complex of 1,2- Bis(Salicylidin Aminooxy) Ethane As an Ionophore


Ali Homafar 1,*, Farzad Maleki 2, Zahra Abbasi 3
1 Department of Chemistry, Eyvan-e-Gharb Branch, Islamic Azad University, Eyvan, Iran
2 Department of Chemistry, Payame Noor University, PO Box 19395-4697 Tehran, Iran
3 Young Researchers and Elite Club, Ilam Branch, Islamic Azad University, Ilam, Iran

ABSTRACT

A PVC membrane electrode for lead ion based on 1,2- bis(salicylidin aminooxy) ethane as a neutral carrier was prepared. The electrode exhibits a near Nernstion response (26/49±0/7 mv/decade) for lead ion over a relatively wide concentration rang (1/0×10-6 to 1/0×10-1) with a limit detection 7/6×10-7M. It has a releatively fast reasponse time (<10 s). The proposed membrane electrode revealed very good selectivity in the PH= 4-7. The influence of membrane composition enthe electrode response was studied. The proposed electrode was used for the determination of lead ion in wastewater, water and wastewater of manufactory.

KEYWORDS
Wastewater, PVC Membrane, Lead, Ion Selective Electrode, Schiff Bases

Cite This Paper in IEEE or APA Citation Styles
(a). IEEE Format:
[1] Ali Homafar , Farzad Maleki , Zahra Abbasi , "Lead (II)-Selective Polymeric Electrode Using PVC Membrane Based on a Schiff Base Complex of 1,2- Bis(Salicylidin Aminooxy) Ethane As an Ionophore," Energy and Environmental Engineering(CEASE PUBLICATION), Vol. 1, No. 3, pp. 99 - 104, 2013. DOI: 10.13189/eee.2013.010301.

(b). APA Format:
Ali Homafar , Farzad Maleki , Zahra Abbasi (2013). Lead (II)-Selective Polymeric Electrode Using PVC Membrane Based on a Schiff Base Complex of 1,2- Bis(Salicylidin Aminooxy) Ethane As an Ionophore. Energy and Environmental Engineering(CEASE PUBLICATION), 1(3), 99 - 104. DOI: 10.13189/eee.2013.010301.